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A new layered metal-organic framework as a promising heterogeneous catalyst for olefin epoxidation reactions
Journal article

A new layered metal-organic framework as a promising heterogeneous catalyst for olefin epoxidation reactions

Jingming Zhang, Ankush V Biradar, Sanhita Pramanik, Thomas J Emge, Tewodros Asefa and Jing Li
Chemical communications (Cambridge, England), Vol.48(52), pp.6541-6543
07/04/2012
DOI: https://doi.org/10.1039/c2cc18127d
PMID: 22622134

Abstract

A new layered MOF material [Co(Hoba)(2)·2H(2)O] (1) (H(2)oba = 4,4'-oxybis(benzoic acid)) has been synthesized and used as a highly recyclable heterogeneous catalyst for olefin epoxidation reactions. Both high conversion (96%) and high selectivity of epoxide products (96%) are achieved.

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