Abstract
Phys. Rev. Lett., vol. 78, 543-546 (1997) Single crystalline (Bi,Ca)MnO3 (74< %Ca <82) were studied with neutron
scattering, electron diffraction and bulk magnetic measurement. We discovered
dynamic ferromagnetic spin correlations at high temperatures, which are
replaced by antiferromagnetic spin fluctuations at a concomitant charge
ordering and structural transition. Our results indicate that thermal-activated
hopping of the Jahn-Teller active e_g electrons in these insulating materials,
nevertheless, induce ferromagnetic interaction through double-exchange
mechanism. It is the ordering of these charges competing with the
double-exchange ferromagnetic metallic state.